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基于紫精羧酸和SCN-离子构建的一维铜配位聚合物的合成、结构及光谱学研究.pdf
35 ,5 Vol.35 ,No.5 , 1340-1344
pp
2 0 1 5 5 Spectroscopy and Spectral Analysis May,2015
Synthesis ,Structure and Spectroscopy Study of a 1D Copper
Coordination Polymer Based on a Carboxybenzyl
Viologen Ligand and SCN-Anion
1 1 1 1 ,2 * 1 * 1
QIU Li-xia ,WAN Fang ,ZHU Bin-bin ,SUN Yan- iong ,YOU Yi ,CHEN Yi- ingq p
1 .Department of Chemistry , Fuzhou University , Fuzhou 350108 ,China
2 .State Key Laboratory of Structural Chemistry , Fujian Institute of Research on the
Structure of Matter,Chinese Academy of Sciences, Fuzhou 350002 , China
Abstract A zwitterionicviologen derivative ligand, 1 ,1’-bis(4-carboxybenzyl) -4 ,4’-bipyridinium dichloride
2 2
(H BpybcCl ) as a multifunctionalligand,hasbeen synthesizedincorporating a4 ,4’-bipyridinecorewith two
carboxylategroups as a building block, specifically designed for the rational construction of metal-organic
2 2
frameworks.H BpybcCl ligandis amultifunctionalligand that containsviologen’s specificfunctionsandcar-
boxylatecoordination groups.The coordination polymers of viologen carboxylate with copper thiocyanate are
not reported to date.A novel coppe
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