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2202_ftp.pdf
www.advmat.de
www.MaterialsV
N High Effi ciency Quantum Dot Heterojunction Solar Cell
O
I
T Using Anatase (001) TiO Nanosheets
A 2
C
I
N Lioz Etgar,* Wei Zhang, Stefanie Gabriel, Stephen G. Hickey, Md K. Nazeeruddin,
U
M Alexander Eychmüller, Bin Liu, and Michael Grätzel
M
O
C
Quantum dots (QDs) have attracted a lot of attention due and a thickness of ∼ 7 nm, and big nanosheets consist of a side
to their tunable bandgap and their high optical absorption length of 60–80 nm and a thickness of ∼ 8 nm. The PbS QDs
cross section.[1–3] A variety of research projects attempt to in this heterojunction solar cell act as an absorber and at the
integrate QDs into solar cells devices, including nanocrystal same time as a hole conductor, rendering superfl uous the use
(NC)-poly mer hybrid solar cells, NC-Schottky solar cells, NC- of an additional p-type material for transporting positive charge
sensitized titanium dioxide (TiO2 ) solar cells, and NC hybrid carriers. This simple PbS QD/TiO2 nanosheets heterojunction
bilayer solar cells.[4–12] Recently investigations focus on QD solar cell achieved a remarkable short circuit current density
heterojunction solar cells, by placing oxide NCs (TiO2 or ZnO) (J sc) of 20.5 mA cm− 2 and a light to electric power conversion
as a thin spacer layer between the QDs and the FTO.[13–19] In effi ciency (PCE) of 4.73% under 0.9 sun intensity. This is t
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