卟啉敏化太阳能电池研究进展有机化学.pdfVIP

DOI: 10.6023/cjoc201412018 综述与进展 有机化学 Chinese Journal of Organic Chemistry REVIEW 卟啉敏化太阳能电池研究进展 顾承志a,b 孟舒献a 冯亚青*,a,c (a 天津大学化工学院 天津 300072) (b 石河子大学化学化工学院 石河子 832000) (c 天津化学与化工协同创新中心 天津 300072) 摘要 由于自然界中光合作用的核心结构是卟啉, 其具有良好的光、热和化学稳定性, 在过去的二十年中卟啉染料敏 化太阳能电池研究获得了极大的关注, 2014 年卟啉染料光电转换效率突破了 13%, 成为新的基准效率. 以光电性能为 主线, 从分子工程设计的角度出发, 系统性地总结了应用于敏化太阳能电池的不同结构卟啉染料性能的研究进展. 关键词 染料敏化太阳能电池; 卟啉; 分子工程设计; 光电性能 Progress of Porphyrin Sensitizers for Dye-Sensitized Solar Cells Gu, Chengzhia,b Meng, Shuxiana Feng, Yaqing*,a,c a ( School of Chemical Engineering, Tianjin University, Tianjin 300072) b ( School of Chemistry and Chemical Engineering, Shihezi University, Shihezi 832000) c ( Collaborative Innovation Center of Chemical Science and Engineering, Tianjin 300072) Abstract As a core structure of nature photosynthesis, porphyrin has good light, thermal and chemical stability. In the past two decades, porphyin based dye-sensitized solar cells (DSSC) has attracted much attention relevant to global environmental issues. Up to date, they exhibit the best performance with a benchmark efficiency of 13% reported in 2014 for dye-sensitised solar cells. The progress of porphyrins and their derivatives applied in DSSC from the point of view of molecular engineerin