吡喃盐化合物的合成及应用研究进展有机化学.pdfVIP

DOI: 10.6023/cjoc201409023 综述与进展 有机化学 Chinese Journal of Organic Chemistry REVIEW 吡喃盐化合物的合成及应用研究进展 叶俊伟 王潇潇 高 远 杨立健 林 源 宁桂玲* (大连理工大学化工与环境生命学部化工学院 精细化工国家重点实验室 大连 116024) 摘要 吡喃盐是一类具有独特化学反应活性和光物理性质的杂环化合物, 在有机合成、生物传感和光电材料等许多领 域展现了良好的应用前景. 结合本课题组的研究成果, 综述了 α-非活性吡喃盐和 α-活性吡喃盐化合物的合成研究进展, 并介绍了一些典型吡喃盐化合物在有机合成、光敏剂、离子液体和荧光传感材料等领域的应用. 关键词 吡喃盐; 合成; α-活性; α-非活性 Research Progress on the Synthesis and Application of Pyrylium Salts Ye, Junwei Wang, Xiaoxiao Gao, Yuan Yang, Lijian Lin, Yuan Ning, Guiling* (State Key Laboratory of Fine Chemicals and School of Chemical Engineering, Faculty of Chemical, Environmental and Biological Science and Technology, Dalian University of Technology, Dalian 116024) Abstract Pyrylium salts are a type of heterocyclic compounds with unique chemical reactivity and photophysical properties. They show great potential applications in the many fields such as organic synthesis, biosensor and organic optoelectronic materials. Based on our recent research results, in this review, the developments in the synthesis of both α-non-active pyrylium salts and α-active pyrylium salts are summarized, and the applications of some typical pyrylium salts in the organic synthesis, photosensitizers, ion liquid and fluorescent sensor are exemplified. Keywords pyrylium salts; synthesis; α-active; α-non-active 吡喃盐又称作吡喃鎓盐, 是由吡喃盐阳离子和作为 料、激光材料、Q-开关材料、有机发光材料和非线性光 抗衡离子的路易斯酸阴离子组成的六元氧杂环化合物. 学材料等领域都得到广泛应用[7～11]. 此外, 近年来,