光学透明、低热膨胀性的甲壳素纳米纤维聚醚砜复合薄膜.pdfVIP

科技导报2014，32（4/5） 光学透明光学透明、、低热膨胀性的甲壳素纳米低热膨胀性的甲壳素纳米 纤维纤维//聚醚砜复合薄膜聚醚砜复合薄膜 邓巧云，李大纲，邵旭，胡琴琴，李晶，陈楚楚 南京林业大学材料科学与工程学院，南京210037 摘要摘要 通过化学预处理和机械处理的方法制备出甲壳素纳米纤维，再利用真空抽滤的方法制备出甲壳素纳米纤维膜，将所得的 纳米纤维素浸渍到聚醚砜树脂中，制备了甲壳素纳米纤维/聚醚砜复合薄膜。采用场发射扫描电镜（FE-SEM）对机械处理的甲壳 素纳米纤维的形态特征进行表征。采用紫外光分光光度计、热机械分析仪（TMA）分别对甲壳素纳米纤维/聚醚砜复合膜的透光 性、热膨胀性做分析，用万能力学试验机测试甲壳素纳米纤维/聚醚砜复合膜的拉伸性能。结果表明，机械处理后，甲壳素纤维达 到纳米级别，随机械处理手段增加，甲壳素纳米纤维直径逐步变小。甲壳素纳米纤维/聚醚砜复合薄膜保持了较高的透光率，对比 树脂材料，热稳定性和力学强度明显增强，是一种具有高透光性、低热膨胀性的复合膜，在光学基底材料、显示器等方面具有较大 的应用潜力。 关键词关键词 甲壳素纳米纤维；聚醚砜；复合薄膜；机械处理；透光率；拉伸强度 中图分类号中图分类号 TB332 文献标志码文献标志码 A doidoi 10.3981/j.issn.1000-7857.2014.h1.006 ChitinNanofiber/PolyetherSulfoneCompositeFilmswithHigh TransparentandLowCoefficientofThermalExpansion DENGQiaoyun,LIDagang,SHAOXu,HUQinqin,LIJing,CHENChuchu CollegeofMaterialsScienceEngineering,NanjingForestryUniversity,Nanjing 210037,China AbstractAbstract Chitin nanofibers were prepared by chemical pretreatment and mechanical treatments. The obtained nanofiber solution formed films through vacuum filtration, and then they were impregnated into polyether sulfone (PES) resin to prepare the chitin nanofibers/PEScompositefilms.Themorphologyofthenanofiberswascharacterizedbyfieldemissionelectronmicroscopy(FE-SEM). Thelighttransmittanceandthermalexpansionpropertiesofthechitinnanofiber/PEScompositefilmwereinvestigatedbyUV-visible spectrometer and thermomechanical analysis. The tension properties of the chitin nanofiber/PES composite film were tested by a universalmaterialsmechanicaltestingmachine.Theresultsshowedthatthediameterofthechitinfibersreachedthenanometerlevel, and with the combination of the mechanical processing method, the diameter of the chitin nanofibers gradually decreased. Chitin nanofiber composite films maintained high light transmittance, and compared with the resin matrix, their thermal stability and mechanical strength were apparently enhanced. Chitin nanofiber composite films possess high light transm