JCM-180高效重油助剂的研制与应用-催化年会征文学案.doc

. 第一作者简介：姚华、(1970-), 男, 湖南省南县人，本科, 高级工程师, 主要从事FCC催化剂及助剂的研究与工业化应用。zhengshuqin37@. 基金来源：科技型中小企业技术创新基金(立项代码：10C26214302487；批准文号：国科发计字【2010】280号） 技术来源：专利号： JCM-180渣油催化裂化助剂的研制 姚华1，郑淑琴1， （1. 湖南， 410600；2. 化学化工学院，） 摘 要: 这种高效重油裂化助剂主要表现在分子筛含量高、抗磨损能力活性高、重油转化能力抗重金属能力强、焦炭选择性好、液收和轻油收率高、汽油烯烃含量低，辛烷值高等显著特点 关键词：重油催化裂化　助剂　活性 ON A NOVEL HEAVY OIL FCC ADDITIVE Yao Hua1, Zheng Shuqin1，2,Yang Guangjun1, （Hunan Juli catalyst Co.,Ltd，Changsha 410600；Department of Chemistry and Chemical Engineering, Hunan Institute of Science and Technology, Yueyang 414000, China） Abstract A novel FCC additive prepared by advanced technologies was developed for heavy oil catalytic cracking. The FCC additive is a high-performance heavy oil additive. The catalystic composite material containing microporous NaY zeolite has been hydrothermally synthesized by in-situ crystallization using sepiolite and kaolin. The additive can be prepared through modification the composite materials. This additive has better sphericity, bigger surface area and pore volume, higher activity and heavy oil crackability, higher totle liquid product yield and light liquid product yield, higher octane and better coke selectivity, lower olefin content, and better anti heavy metal performance. The additives can be widely used in heavy oil residue catalytic cracking unit. The additive exhibited better catalytic performance and can replace imports. The additive possess the technical competitive advantages to export the international market. Key Words : Heavy oil catalytic cracking; additive; in-situ crystallization; activity 随着炼油工业的不断发展，FCC（流化催化裂化）日益成为石油深度加工的重要手段，以催化裂化催化剂及助剂为核心技术的FCC（流化催化裂化）工艺已成为原油二次加工的主要手段，在炼油工业中占有举足轻重的地位。FCC（流化催化裂化）工艺是将重质油轻质化，目的产品是汽油、柴油和液化气。由于FCC（流化催化裂化）工艺使产品转化率高，产品质量好，因此近半个世纪以来，FCC工艺技术和生产规模都有了很大的发展，随着催化裂化技术的创新，裂化催化剂及助剂也在不断改进与发展，催化裂化工艺技术也在进一步发展和改进。催化裂化已经成为我国炼油工业的核心技术和石油化工企业经济效益的主要支柱。据统计，目前全球FCC加工能力已达7.54亿吨/年。而近年来的世界原油重质化日趋严重，FCC（流化催化裂化重油流化催化裂化1亿吨/年。在原油质量变重变差的同时，世界对轻质油产品需求却在日益增多。因此，重质油和渣油轻质化的加工技术和方案已成为炼油工业面向21世纪令人关