邓文宾毕业论文R3邓文宾毕业论文R3.doc

本科生毕业设计（论文） 题 目：d10金属配合物与卤化镉异金属杂化分子的合成与力诱导变色行为研究041002304 学 院： 化学学院 专 业： 化学类 年 级： 2010级 指导教师： （签名） 2014年 5 月 26 日 d10金属配合物与卤化镉异金属杂化分子的合成与力诱导变色行为研究 中文摘要 基于异金属结构的功能材料由于复合了多种金属和有机配体的性能在新型功能材料如信息储存和传递、的研究尚处于起步阶段。 (1)。化合物晶体结构由X-射线单晶衍射仪确定，并用红外光谱（IR）、固体紫外－可见漫反射光谱和荧光分析对产物进行表征。结构解析表明，Synthesis and Mechanochromic Behaviro of New Heterometallic Hybrid Constructed from d10 Metal Complex and Cadmium Halide Abstract Due to the performance of the composite of a variety of metal and organic ligands ,functional materials based on the structure of different metal shows attractive application prospect in new functional materials such as information storage and transmission, photocatalysis, magnetic materials, and other fields . We can obtain materials with novel structure, performance and special functional by means of adjusting and controlling the structure of coordination compound in chemical means. 　　　As a result of organic pollutants (pops) having great harm to human health and environment, the materials of photocatalytic degradation ,which based on metal organic framework, is a hotspot of research on recent functional complexes. 　　　While research ,applying the compound about d10 metal and metal halide to the field of photocatalytic degradeing organic pollutants, is still in its infancy. In this thesis, we complex 1,10-Phenanthroline/Cd coordination compound with cuprous iodide together to get a novel hybrid functional molecules {[Cu (phen) 2 I] 2 (CdI4)} n (phen = 1, 10 - Phenanthroline) (1) by hydrothermal synthesis method . Crystal structure of Compound 1 is determined by X-ray single crystal diffraction, and the product were characterized by infrared spectrum (IR), solid ultraviolet-visible diffuse reflection spectra and fluorescence analysis . Structure analysis showed that the compound 1 is comprised by d10 metal coordination compound kation [Cu(p