CYTEC Why Did My Product Turn Yellow.pdf

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CYTEC Why Did My Product Turn Yellow

Why Did My Product Turn Yellow? And Other Questions You Should Never Need To Ask G. Vitarelli, L. Davis, P. Arnaboldi, S. Samuels Cytec Industries Pan European Conference on Rotational Molding, Euro Disney, May 2002 ? Where is color change expected? ? Why do plastics form or change color? ? What creates or causes color in plastics? ? What can You do to stop or limit color? ? Who can help? Pan European Conference- Paris - 05. 2002 ?2002 Cytec Industries Inc., All Rights Reserved Color in Polyolefins ? YELLOWING ? PINKING ? BLACK SPECKS ? FADING ? COLOR CHANGE Pan European Conference- Paris - 05. 2002 ?2002 Cytec Industries Inc., All Rights Reserved Resin ? Polymer ? Density ? Melt index ? Catalyst Pan European Conference- Paris - 05. 2002 ?2002 Cytec Industries Inc., All Rights Reserved Additives ? Antioxidant (AO) ? Ultraviolet Light Stabilizer (UV) ? Antacid ? Modifier ? Pigment Pan European Conference- Paris - 05. 2002 ?2002 Cytec Industries Inc., All Rights Reserved Color From Primary AO ? AO + AO ? AO + NOx + HALS ? AO + metal ion (from pigment or catalyst) ? AO from cardboard box ? PINKING or YELLOWING Pan European Conference- Paris - 05. 2002 ?2002 Cytec Industries Inc., All Rights Reserved Color from Coupling of BHT OH O O O Pan European Conference- Paris - 05. 2002 ?2002 Cytec Industries Inc., All Rights Reserved Color from Oxidative Coupling of AO OH CO2R O CO2R CO2R O O CO2R CO2R O Oxidative Coupling Red color Base AO 1010 R=neopentyl AO 1076 R=C18H37 Pan European Conference- Paris - 05. 2002 ?2002 Cytec Industries Inc., All Rights Reserved Antioxidants Resistant to Discoloration OH R 3 AO 1790 OH R 3 AO 1741 N N N O O O R= Pan European Conference- Paris - 05. 2002 ?2002 Cytec Industries Inc., All Rights Reserved NOx Catalyzes Oxidation of Phenols R OH R R O R NO O R R+NOx -NO O R R 2 O R R O R R Pan European Conference- Paris - 05. 2002 ?2002 Cytec Industries Inc., All Rights Reserved Oxidation of Nondiscoloring AO by NOx R OH R R R O R NO R O R R

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