catalogue_titanocene.pdf

Ever Researching for a Brighter World NICHIA CORPORATION Technical Data Ti ClCl Ever Researching for a Brighter World CONTENTS １． General Features ２． Product Guide ３． Solubility in Various Solvents ４． Solubility in Water and ｐH ５． Stability ６． Decomposition Mechanism ７． Applications (Examples) ８． Application in Organic Synthesis (Examples) ◆ Synthesis of Methylenation Reagent ◆ Methylenation of Aldehydes, Ketones, Esters, Lactones, and Amides ◆ Cp2 TiCl2 -Catalyzed Carbometalation of Alkynols ◆ π-Allyl titanium Compounds in Organic Synthesis ◆ Hydroalumination of Olefins Catalyzed by Cp2 TiCl2 ◆ Hydrogenolysis of Allylalcohols Catalyzed by Cp2 TiCl2 ◆ Isomerization Catalyzed by Cp2 TiCl2 ◆ Olefin Metathesis Catalyzed by Cp2 TiCl2 ◆ Hydrogenation of Olefins and Conjugated Diolefins Catalyzed by Cp2 TiCl2 ◆ Cp2 TiCl2 -Catalyzed Reduction Using Grignard Reagent ◆ Grignard Exchange Reactions of Alkenes, Dienes and Alkynes ◆ Preparation of Titanacyclopentenes and –pentadienes Using Cp2 TiCl2 ◆ Double C-C Bond Cleavage of Cyclopentadienyl Ligand ◆ Enyne Cyclization by Cp2 TiCl2 ◆ Reductive Opening of Epoxides ◆ Carbosilylation of Alkenes and Dienes Using Alkyl Halides and Chlorosilanes ◆ Regioselective Syn-Hydrosilation of Alkynes ９． Storage and Safety Handling etc． １．General Features （１） Titanocene Dichloride highly acts on the unsaturated compounds and shows excellent effects as an active homogeneous hydrogenation catalyst under moderate conditions. （２） Titanocene Dichloride improves stereo regularity due to the effect of cyclopentadienyl group. （３） Titanocene Dichloride can be widely used for various derivatives which become the basic materials for high performance chemical products. （４） Consistently high/uniform quality has been realized by