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SrBi4Ti4O15的铁电相变和铁电性-中国有色金属学报
25 9 2015 9
Volume 25 Number 9 The Chinese Journal of Nonferrous Metals Sep. 2015
1004-0609(2015)-09-2501-09
SrBi Ti O
4 4 15
(() 266580)
SrBi Ti O (SBTi)(EET)
4 4 15
SrBi Ti O (SBTi)SBTi
4 4 15
−(Aama)(I4/mmm)
SBTi a
25.81 μC/cm2
O641.1 A
Ferroelectric phase transition and
ferroelectricity of SrBi Ti O
4 4 15
XIAO Xiao-hong, LI Shi-chun
(College of Mechanic and Electronic Engineering,
China University of Petroleum (East China), Qingdao 266580, China)
Abstract: The chemical bonds structures were analyzed by the atomic environment calculation method, and the valence
electron structure of orthorhombic phase SrBi Ti O was calculated according to the EET theory, the numbers of the
4 4 15
effective valence electrons of each atom in SrBi Ti O were obtained. Furthermore, according to the theory of crystal
4 4 15
space group, the structures of orthogonal paraelectric phase (Aama) and the tetragonal paraelectric phase (I4/mmm) in the
ferroelectric−paraelectric phase transition were constructed, and the atomic displacements in the phase transition were
calculated by the atomic coordinate an
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