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Tx100增敏碲化镉量子点荧光猝灭法分析诱惑红
Hans Journal of Chemical Engineering and Technology 化学工程与技术, 2016, 6(3), 43-54
Published Online May 2016 in Hans. /journal/hjcet
/10.12677/hjcet.2016.63006
Determination of Allura Red by Tx-100
Sensitization CdTe QDs Fluorescence
Quenching Method
Liu Ye, Xiashi Zhu
College of Chemistry Chemical Engineering, Yangzhou University, Yangzhou Jiangsu
th st th
Received: Apr. 29 , 2016; accepted: May 21 , 2016; published: May 24 , 2016
Copyright © 2016 by authors and Hans Publishers Inc.
This work is licensed under the Creative Commons Attribution International License (CC BY).
/licenses/by/4.0/
Abstract
The fluorescence quenching effect of Allura red on the water-soluble CdTe quantum dots (CdTe
QDs) in surfactant Tx-100 medium was investigated. Based on the Tx-100 sensitization CdTe QDs
fluorescence quenching, a novel method for the determination of Allura red was proposed. Under
the optimal conditions, the relationship of Allura red concentration in the 0.6 - 60.0 µg/mL range
and CdTe QDs fluorescence quenching value was linear. The linear regression equation and the
linear correlation were ΔF = 12.86c-77.36 (c:µg/mL) and 0.9939, respectively. The limit of detec-
tion was found to be 0.35 µg/mL (the definition of limit of detection was LOD = 3σ/k, where σwas
the standard deviation and k was the slope of the standard curve). The sensitized mechanism and
fluorescence quantum yield in different media were discussed preliminarily. The method has been
applied to the determination of Allura red in samples with satisfactory results.
Keywords
Allura Red, Cadmium Telluride Quantum Dots, Tx-100, Sensitization, Fluorescence Quenching
Tx-100增敏碲化镉量子点荧光猝灭法
分析诱惑红
叶 柳,朱霞石
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