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气相色谱专家系统柱推荐软件之四――无机气体和轻烃采用气相色谱分析时最佳固定相的推荐软件
669(1986). Pharmacy,110015
[8] D.R.Deans,I.Scott,Anal.Chem.,45(7).1137 A serialiy connected binary gas chromatographic
(1973).
capillary column system has been established based
[9] R.E.Kaiser,L.Leming,L.Blomberg,R.I.Rieder,
upon a Model HP-5890 Gas Chromatograph.Dead
HRC&CC,8,92(1985).
time,relative retentivity and the capacity factor of a
[10] L.Leming,R.E.Kaiser,Abstracts of BeijingConference
solute in the binary-column system were calculated
and Exhition on Instrumental Analysis,Beijing,China,
from the operating parameters as Pi,Pa and Po using
239,1985.
several model substances.A regression equation
[11] I.H.Purneil,P.S.Williams,J.Chromatogr.,292,174
(1984). (ks ) was derived based on relative retentivity
[12] M.L.Pcterson,U.Hirsch,J.Lipid Ros.1,132 and the capacity factor of a solute in the binary-col-
(1959). umn system and is used for retention calculation.The
(收稿日期1991年9月29日,修回日期:12月26日) results obtained for the model compounds were com-
pared with the measured values in the individual Col-
Qualitative Analysis by Using a Serially Con- umn.The maximum errors on OV-1(bonded)and on
nected Binary Gas Chromatographic Capillary PEG-20M (bonded) were 2 and 5 index units,re-
Wang An,Tianjin Institute of Pharmaceutical spectively.
Research,300090;Sun Yuqing,Shenyang College of
气相色谱专家系统柱推荐软件之四*
——无机气体和轻烃采用气相色谱分析时
最佳固定相的推荐软件
许国旺 张玉奎 卢佩章
(中国科学院大连化学物理研究所 国家色谱研究
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