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功能化的离子液体手性离子液体的合成与应用刘伟山.pdf

功能化的离子液体手性离子液体的合成与应用刘伟山.pdf

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功能化的离子液体手性离子液体的合成与应用刘伟山

2006 26 Vol. 26, 2006 8 , Chinese Journal of Organic Chemistry No. 8, ·· : * ( 100871) . , , , . , . , . ; ; ; ; Functional Ionic Liquids: Synthesis and Application of Chiral Ionic Liquids LIU, Wei-Shan TAO, Guo-Hong HE, Ling KOU, Yuan* (State Key Laboratory for Structural Chemistry of Unstable and Stable Species, Green Chemistry Centre, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871) Abstract Chirality shows an important role in chemistry. Ionic liquids have a special character different from common organic solvents for their alterable structures. Chiral ionic liquids can be gotten when chirality is induced to ionic liquids. They may be used to chiral synthesis, chiral separation, or chiral catalysis. Those chiral ionic liquids reported before are presented in this review, and discussed especially from the viewpoint of designing functionalized ionic liquids. Three criteria for designing and synthesizing ionic liquids from natural chiral materials are brought out. Keywords ionic liquid; functionalized; chiral; synthesis; application . , , , [6]. . [1]. . , / , , , , [24] . [7,8]. . [5] ,

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