配位化学的进展（Progress in coordination chemistry）.doc

配位化学的进展（Progress in coordination chemistry） Progress in coordination chemistry Coordination chemistry is an interdisciplinary subject developed on the basis of inorganic chemistry. The main object of study is coordination compound (Coordination, Compounds). Early coordination chemistry was focused on the so-called Werner complexes formed with metal cation receptors as the center (as acids) and ligands (as bases) of donor atoms such as N, O, S, P and so on. During the Second World War, inorganic chemists develop in the synthesis of some elements in the periodic table of elements around the compound, in the industry, the United States implemented Manhattan nuclear fission (Manhattan) complexes in the development of Engineering on the basis of uranium and transuranics solution. In discipline, the synthesis of two valent iron by Panson and Miler broke the boundaries between traditional inorganic and organic compounds in 195l, thus beginning the revival of inorganic chemistry. Contemporary coordination chemistry develops in three directions: breadth, depth and application. At depth, scholars with numerous coordination chemistry have won the Nobel prize, such as the creation of a coordination chemistry for Werner, a metal olefin catalyst for Ziegler and Natta, and a rapid reaction of Eigen. Lipscomb borane theory, metal organic chemical Wnkinson and Fischer development, Hoffmann equivalve theory, Taube research complexes and reaction mechanism of nitrogen fixation, Cram, Lehn and Pedersen contribution in the field of supramolecular chemistry, the electron transfer process of Marcus. On the basis of their pioneering achievements, coordination chemistry has made a series of advances in its synthesis, structure, properties and theoretical studies. In the breadth in performance since Werner created the coordination chemistry, coordination chemistry in the mainstream research of inorganic chemistry, coordination compounds with its variety of valence form and spatial structure,