含柔性侧链苯并菲衍生物合成研究的进展AdvancesintheSynthesis.PDF

See discussions, stats, and author profiles for this publication at: /publication/216528416 Advances in the synthesis of triphenylene derivatives with flexible side chains Article in Chinese ournal of Organic Chemistry · April 2006 CITATIONS READS 13 59 3 authors, including: Zhiqun He Beijing iaotong University 92 PUBLICATIONS 897 CITATIONS SEE PROFILE All content following this page was uploaded by Zhiqun He on 13 September 2014. The user has requested enhancement of the downloaded file. 2006 年第 26 卷 有 机 化 学 Vol. 26, 2006 第 4 期, 413～418 Chinese Journal of Organic Chemistry No. 4, 413～418 ·综述与进展· 含柔性侧链苯并菲衍生物合成研究的进展 毛华香 何志群* 张春秀 (北京交通大学光电子技术研究所 北京 100044) 摘要 系统地综述了含柔性侧链苯并菲衍生物的合成方法的研究进展. 根据苯并菲取代基的特点来划分合成苯并菲 生物的方法, 并选取具有代表性的实例对苯并菲衍生物的结构和合成方法进行详细的阐述. 关键词 合成; 对称; 非对称; 苯并菲衍生物 Advances in the Synthesis of Triphenylene Derivatives with Flexible Side Chains MAO, Hua-Xiang HE, Zhi-Qun* ZHANG, Chun-Xiu (Institute of Optoelectronic Technology, Beijing Jiaotong University, Beijing 100044) Abstract This paper reviews the synthetic methods for triphenylenes with flexible side chains. The meth- ods are classified according to the structural characteristics. A number of examples are selected to illustrate the target structures and the synthetic methods. Keywords synthesis; symmetry; unsymmetry; triphenylene 由三个苯环组成的苯并菲化合物最早是从苯的热 烷烃侧链之间的范德华力相互作用而堆积成柱[6], 由 裂 解 产 物 中 分 离 出 来 , 并 由 Schultz 首 先 称 之 为 柱内分子电子云的相互交叠,