抚顺油页岩及其残渣的热解性能-JournalofNortheasternUniversity.PDF

第29卷第10期 东 北 大 学 学 报 ( 自 然 科 学 版 ) Vol29, No. 10 200 8 年 10 月 Journal of Northeastern U niversity( Natural cience) Oct. 2 0 0 8 薛向欣, 李 勇, 冯宗玉 ( , 110004) : , : ~ 200 , , 2446% 3202% ; 200~ 600 , , 16048% 6524% Coats- Redfern , 5184 2814 kJ/ mol, 6235 0003 25 min- 1; 3662 5505 kJ/ mol, 0009 760341 min- 16524% : ; ; ; ; : T Q 530. 2 : A : 1005-3026( 2008) 10- 1447-03 On the Pyrolytic Properties of Fushun Oil Shale and Its Residue X UE X iang-x in , L I Yong , FEN G Zong-y u ( chool of Materials and Metallurgy, Northeastern University , henyang 110004, China. Correspondent: XUE Xiang-xin, E-mail: xuexx @ mail. neu. edu. cn) Abstract: A thermogravimetric analysis was made to investigate the pyrolytic properties of the Fushun oil shale and its residue. T he results show ed that their pyrolytic reaction can be divided into tw o processes. The first one is mainly the moisture volatilization w ithin the range from room temperature to 200 , then the moisture volatilization contents in the oil shale and its residue are 2. 446% and 3. 202% , respectively . The second one is mainly the pyrolysis of fixed carbon between 200 and 600 , then the rates of weight loss of oil shale and its residue are 16. 048% and 6. 524% , respectively. And the Coats-Redfern method is used to get the kinetic constant in pyrolytic reaction. Correspondingly, the activation energies of the kerogen shale are 51. 84 and - 1 28. 14 kJ/ mol, and the frequency factors are 62. 35 and 0. 003 25 min , respectively. The activation energies of oil shale residue are 36. 62 and 55. 05