CeCl3作为优秀的试剂在有机合成中的应用必威体育精装版进展 Applications of CeCl3 as an Environmental Friendly Promoter in Organic Chemistry.pdf

Chem. Rev. XXXX, xxx, 000–000 A Applications of CeCl3 as an Environmental Friendly Promoter in Organic Chemistry Giuseppe Bartoli,‡ Enrico Marcantoni,*,† Mauro Marcolini,† and Letizia Sambri‡ School of Science and Technology, Chemistry Division, University of Camerino, via S. Agostino 1, I-62032 Camerino (MC), and Department of Organic Chemistry “A. Mangini”, University of Bologna, viale Risorgimento 4, I-40156 Bologna, Italy Received March 8, 2010 Contents 1. Introduction A 2. Organocerium Compounds in Organic Chemistry D 2.1. Addition to Carbonyl Compounds E 2.2. Addition to Acid Derivatives J 2.3. Addition to Carbon-Nitrogen Multiple Bonds L 2.4. Addition to Carbon-Carbon Multiple Bonds L 2.5. Application in Organic Synthesis M 3. CeCl3 Mediated Reductions M 3.1. Reduction of Carbon-Oxygen Double Bond N 3.2. Reduction of Phosphorus-Oxygen Double S Bond 3.3. Application in Organic Synthesis T 4. CeCl · 7H O-NaI System in Bond-Forming U Giuseppe Bartoli graduated from the University of Bologna in 1967 with 3 2 Reactions a Laur