Current Analytical Chemistry, 103-119 103 Porphyrin Based :目前的分析化学,103 103-119卟啉类.pdf

Current Analytical Chemistry, 103-119 103 Porphyrin Based :目前的分析化学,103 103-119卟啉类.pdf

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Current Analytical Chemistry, 103-119 103 Porphyrin Based :目前的分析化学,103 103-119卟啉类

Current Analytical Chemistry, 2005, 1, 103-119 103 Porphyrin Based Affinity Interactions: Analytical Applications with Special Reference to Open Tubular Capillary Electrochromatography , ˇ * 1 ˇ 1 1 2 3 Zdenek Deyl , Ivan Miksik , Adam Eckhardt , Václav Kasˇ iˇcka and Vladimír Král 1 ˇ Institute of Physiology, Academy of Sciences of the Czech Republic, Víde n ská 1083, 142 20 Prague 4, Czech Republic 2Institute of Organic Chemistry and Biochemistry, Academy of Sciences of the Czech Republic, Flemingovo 2, 166 10 Prague 6, Czech Republic 3Institute of Chemical Technology, Technická 5, 166 28 Prague 6, Czech Republic Summary: This review offers a brief summary of results obtained from separations of the sets of biologically relevant compounds (carboxylic acids, amino acids, peptides, nucleotides and organic phosphates) using open tubular capillary electrochromatography (OT-CEC), in which oligopyrrolic macrocycles serve as the modifiers of the inner fused silica capillary wall surface. Types of interactions leading to improved selectivity of the open tubular capillary electrochromatographic systems and/or to the change of the speed of the electroosmotic flow are also discussed. In addition, selected comparative data on the application of oligopyrrolic macrocycles in other analytical methods, particularly chromatographic and s

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