脂类的氧化_oxidation3培训资料.ppt

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脂类的氧化_oxidation3培训资料.ppt

Chemistry of Lipid Oxidation;Molecular Orbital of Triplet Oxygen;;Hydroperoxide Decompositin ;Mechanisms of Oxidation;Peroxide Decomposition;Effects of Metal on Peroxide Decomposition;C;Lactones in butter flavor;Lactones come from d-hydroxy acids in milk;Lactone Formation;Molecular Orbital of Singlet Oxygen;Excitation and Deactivation of Photosensitizer;Excitation and Deactivation of Photosensitizer;Photooxidation process (RH : Substrate ; K1 = 1 - 3 ? 109 /M ?sec. ; K2 107 /M ?sec);Production of 1O2 by Photochemical, Chemical, and Biological Systems;1,4- Cycloaddition;Reaction of Singlet Oxygen with Double Bond;Conjugated and Nonconjugated Hydroperoxides Arising via the 6-Centered Transition state;Reversion Flavor;4-Keto-6-nonenal Formation from Linolenic Acid;Mechanism for 4-Keto-5-nonenal Formation from 4-Keto-6-nonenal ;Formation of 2-(1-Pentenyl)furan from 4-Keto-5-nonenal and 2-(2-Pentenyl)furan from 4-Keto-5-nonenal;Formation of 2- Pentyl furan;m;Enzymatic lipid oxidation (Lipoxygenase);Specificity of Lipoxygenase;Mechanism of Action ;m;m;Aldehyde and Alcohol Formation in Tomato from Linolenic and Linoleic Acid.;m;Ethyl vinyl ketone;H;

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