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凝聚态光物理学第二章
Classical propagation
2.1 Propagation of light in a dense optical medium
2.2 The dipole oscillator model
2.3 Dispersion
3.4 Optical anisotropy: birefringence
2
Chapter 2 Classical propagation
Model:
Light: electromagnetic wave
Atom and molecule: classical dipole oscillator
n(), ()
Two propagation parameters:
n,
2.1 Propagation of light in a dense optical medium
Three types of oscillators:
1. bound electron (atomic) oscillator
2. vibrational oscillator;
3. free electron oscillators
2.1.1 Atomic oscillators
2.1 Propagation of light in a dense optical medium
2.1.1 Atomic oscillators
If = 0, resonant absorption
(Beer’s law)
h = E2 - E1
re-radiated photon – luminesce
radiationless transition
If 0, non-resonant, transparent
The oscillators follow the driving wave,
but with a phase lag. The phase lag
accumulates through the medium and
retards the propagation of the wave
front, leading to smaller velocity than
in free space (v =c / n).
-- the origin of n
2.1.2 Vibrational oscillators
Classical model of a polar molecule
(an ionic optical medium)
Infrared spectral region
In a crystalline solid form the condensation of polar
molecules, these oscillations are associated with
lattice vibrations (phonons).
2.1.3 Free electron oscillators
Free electrons, Ks = 0, 0 = 0
Drude-Lorentz model
2.2 The dipole oscillator model
2.2.1 The Lorentz oscillator
Light wave will drive oscillations at its own
Frequency:
Solution;
The gives:
With:
The macroscopic polarization of medium P:
The electric displacement D:
2.2 The dipole oscillator model
2.2.1 The Lorentz oscillator
low frequency limit:
high frequency:
Thus
Close to resonance:
Frequency dependence of the real and imaginary
Parts of the complex dielectric constant of a dipole
At frequencies
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