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EXPERIMENT #16: CHEMICAL EQUILIBRIUM AND LE CHATELIERS PRINCIPLE
PURPOSE: To study chemical reactions at equilibrium and their responses to stress as described by
Le Chatliers Principle.
INTRODUCTION:
You will study three different equilibrium systems involving ions in solution. The first system is the conversion
of the indicator thymol blue from its blue form to its yellow form. The extent to which the forward reaction is
+
favored depends upon the concentration of hydrogen ions, [H ], in solution:
+
thymol blue (blue form) + H (aq) ⇌ thymol blue (yellow form)
3+ –
The second reaction involves the light yellow iron (III) ion, Fe , and thiocyanate ion, SCN , which forms the
colored complex, FeSCN2+ :
3+ - 2+
Fe (aq) + SCN (aq) ⇌ FeSCN (aq)
The third system involves the hydrated cobalt (II) ion, Co(H O) 2+ , which can be converted to the chlorinated
2 6
complex ion, Co(H O) Cl :
2 4 2
2+ –
Co(H O) (aq) + 2Cl (aq) ⇌ Co(H O) Cl (aq) + 2H O(l)
2 6 2 4 2 2
You will study the effects of changing the temperature on this system. Your data should allow you to predict
whether the forward or rev
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