中国科学院大学-高等有机化学-第九章-硼，硅和锡化合物的碳-碳键形成反应-Carbon-Carbon Bond-Forming Reactions of Compounds of Boron, Silicon, and Tin.ppt

10.2.3.1. Cyclopropanation with Halomethylzinc Reagents. 10.2.3.1. Cyclopropanation with Halomethylzinc Reagents. 10.2.3.2. Metal-Catalyzed Cyclopropanation 10.2.3.5. Enantioselective Cyclopropanation. 10.2.3.5. Enantioselective Cyclopropanation. 10.2.4. Insertion Reactions 10.2.4. Insertion Reactions 10.2.5. Generation and Reactions of Ylides by Carbenoid Decomposition 10.2.6. Rearrangement Reactions 10.2.7. Related Reactions 10.2.7. Related Reactions 10.2.7. Related Reactions 9.3.2.2. Reactions of Allylic Halostannanes 9.3.2.2. Reactions of Allylic Halostannanes 9.3.2.3. Reactions Involving Transmetallation 9.3.2.4. -Oxygen-Substituted Stannanes 9.3.2.4. -Oxygen-Substituted Stannanes 9.3.2.4. -Oxygen-Substituted Stannanes 9.3.2.4. -Oxygen-Substituted Stannanes 9.3.2.5. Enantioselective Addition Reactions of Allylic Stannanes 9.3.2.6. Allenyl Stannanes. 9.4. Summary of Stereoselectivity Patterns Summary of Stereoselectivity of Allylic Reagents in Carbonyl Addition Reactions Chapter 10 Reactions Involving Carbocations, Carbenes, and Radicals as Reactive Intermediates Introduction 10.1. Reactions and Rearrangement Involving Carbocation Intermediates 10.1.1. Carbon-Carbon Bond Formation Involving Carbocations 10.1.1.1. Intermolecular Alkylation by Carbocations 10.1.1.2. Polyene Cyclization 10.1.1.2. Polyene Cyclization 10.1.1.2. Polyene Cyclization 10.1.1.3. Ene and Carbonyl-Ene Reactions 10.1.1.3. Ene and Carbonyl-Ene Reactions 10.1.1.3. Ene and Carbonyl-Ene Reactions 10.1.1.4. Reactions with Acylium Ions 10.1.1.4. Reactions with Acylium Ions 10.1.2. Rearrangement of Carbocations 10.1.2.1. Pinacol Rearrangement 10.1.2.1. Pinacol Rearrangement 10.1.2.3. Rearrangements Involving Diazonium Ions. 10.1.3. Related Rearrangements 10.1.3.1. The Favorskii Rearrangement Mechanism 1 Mechanism 2 10.1.3. Related Rearrangements 10.1.3.1. The Favorskii Rearrangement Mechanism 1 10.1.3.2. The Ramberg-Backlund