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2023/5/231§1-1 Introduction
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2023/5/2324§1-2 Crystal Structure
2023/5/2325Solid state materials includes: insulator, semiconductors and conductors.Semiconductor materials
2023/5/2326Compounds SemiconductorsA binary compound semiconductors is a combination of two elements from the periodic table. Ex: GaAs , GaP……etc.Ternary and quaternary compounds. Ex:GaxIn1-xAsyP1-yElement Compound SemiconductorsElement Semiconductors
2023/5/2327SolidsAs atoms are brought together to form solid, the interaction of the valance electrons hold the crystal together and determine its electrical behavior. Covalent Bond: sharing of a pair of electrons, Si crystal Ionic Bond: transfer of electron , NaClMetallic Bond: Attraction between the ion core and the sea of electrons, AI(FCC)
2023/5/2328 SolidsSolids can be classified as crystal, polycrystalline and amorphousCrystal – three dimensional long range order of atoms.Polycrystalline – medium range order, many small regions called grains, each having crystalline structure, joined at “grain boundaries” which are full of defects.Amorphous – no well defined order .
2023/5/2329Crystal Structure
2023/5/2330 CrystalLattice: The periodic arrangement of points in a crystal.Basis: The constituent atoms attached to each lattice point. Every basis is identical in composition, arrangement, and orientation. Crystal= Lattice+ BasisR=ma+nb+pca: lattice constant
2023/5/2331 CrystalThe lattices is defined by three fundamental translation vectors
2023/5/2332Unit cell: Lattice can be constructed by repeatedly arranging unit cellUnit Cell
2023/5/2333Primitive Cell : A unit cell is called as primitive unit cell if
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